Publications
Peer-Reviewed Publications
bold are Augustyn group students & postdocs, + invited contribution * corresponding author
- M. Chagnot, S. Abello, R. Wang, J. Dawlaty, J. Rodríguez-López, C. Zhang, & V. Augustyn.* “Influence of Finite Diffusion on Cation-Insertion Coupled Electron Transfer Kinetics in Thin Film Electrodes.” Journal of the Electrochemical Society, DOI: 10.1149/1945-7111/ad1d98.
- A.-R. Siddiqui, J. N’Diaye, K. Martin, A. Baby, J. Dawlaty, V. Augustyn, & J. Rodríguez-López.* “Monitoring SEIRAS on a Graphitic Electrode for Surface-Sensitive Electrochemistry: Real-time Electrografting.” Analytical Chemistry, accepted.
- J. Fortunato, B.Z. Zydlewski, M. Lei, N.P. Holzapfel, M. Chagnot, J.B. Mitchell, H.-C. Lu, D.E. Jiang, D.J. Milliron,*+ & V. Augustyn.* “Dual-Band Electrochromism in Hydrous Tungsten Oxide.” ACS Photonics, DOI: 10.1021/acsphotonics.3c00921.
- J.B. Mitchell, M. Chagnot, & V. Augustyn.*+ “Hydrous Transition Metal Oxides for Electrochemical Energy and Environmental Applications.” Annual Review of Materials Research. 53 (2003) 1 – 23.
- J. Fortunato, Y.K. Shin, M.A. Spencer, A.C.T. van Duin, & V. Augustyn.*+ “Choice of Electrolyte Impacts the Selectivity of Proton-coupled Electrochemical Reactions on Hydrogen Titanate.” Journal of Physical Chemistry C, 127 (2023) 11810. (as part of the virtual special issue “Esther Sans Takeuchi Festschrift”)
- W.-Y. Tsai, S. Pillai, K. Ganeshan, S. Saeed, Y. Gao, A. van Duin, V. Augustyn, & N. Balke.* “Effect of electrode/electrolyte coupling on birnessite (δ-MnO2) mechanical response and degradation.” ACS Applied Materials & Interfaces, 15 (2023) 26120.
- M.S. Hossain, A.I.B. Romo, S. Putnam, J. Dawlaty, V. Augustyn, & J. Rodríguez-López.* “Electrode potential driven dissociation of N-heterocycle-BF3 adducts: a possible manifestation of the electro-inductive effect.” Angewandte Chemie, 62 (2023) e202304218.
- V. Kabra, B. Birn, I. Kamboj, V. Augustyn, & P. Mukherjee.* “Mesoscale Machine Learning Analytics for Electrode Property Estimation.” Journal of Physical Chemistry C, 126 (2022) 14413.
- J. Fortunato, J.W. Jordan, G.N. Newton, D.A. Walsh, & V. Augustyn.*+ “Electrochemical Reactivity of Atomic and Molecular Species under Solid-state Confinement.” Current Opinion in Electrochemistry, 34 (2022) 101014. (as part of Emerging Opinions article collection)
- J.B. Mitchell, R. Wang, J.S. Ko, J.W. Long, & V. Augustyn.*+ “Critical Role of Structural Water for Enhanced Li+ Insertion Kinetics in Crystalline Tungsten Oxides.” Journal of the Electrochemical Society, 169 (2022) 030534. (as part of Focus Issue in Honor of Professor John B. Goodenough: A Centenarian Milestone)
- S. Fleischmann,* Y. Zhang, X. Wang, P.T. Cummings, J. Wu, P. Simon,* Y. Gogotsi,* V. Presser,* & V. Augustyn.* “Continuous Transition from Double-Layer to Faradaic Charge Storage in Confined Electrolytes.” Nature Energy, 7 (2022) 222-228.
- M.A Spencer, J. Fortunato, & V. Augustyn.*+ “Electrochemical Proton Insertion Modulates the Hydrogen Evolution Reaction on Tungsten Oxides.” Journal of Chemical Physics, 156 (2022) 064704. (as part of Special Topic on The Chemical Physics of the Electrode-Electrolyte Interface)
- S. Saeed, J. Fortunato, K. Ganeshan, A.C.T. van Duin, & V. Augustyn.*+ “Decoupling Proton and Cation Contributions to Capacitive Charge Storage in Birnessite in Aqueous Electrolytes.” ChemElectroChem, 8 (2021) 4371. (as part of Joint Special Collection in Honor of Prof. Jean-Michel Savéant)
- M.A. Spencer, O. Yildiz, I. Kamboj, P.D. Bradford, & V. Augustyn.* “Toward Deterministic 3D Energy Storage Electrode Architectures via Electrodeposition of Molybdenum Oxide onto CNT Foams.” Energy & Fuels, 35 (2021) 16183.
- S. Boyd, K. Ganeshan, W.-Y. Tsai, T. Wu, S. Saeed, D.-E. Jiang, N. Balke, A.C.T. van Duin, & V. Augustyn.* “Effects of Interlayer Confinement and Hydration on Capacitive Charge Storage in Birnessite.” Nature Materials, 20 (2021) 1689.
related: “News & Views” in Nature Materials by Yury Gogotsi & Patrice Simon, “Confined water controls capacitance“ - S. Saeed, S. Boyd, W.-Y. Tsai, R. Wang, N. Balke, & V. Augustyn.*+ “Understanding Electrochemical Cation Insertion into Prussian Blue from Electrode Deformation and Mass Change.” Chemical Communications, 57 (2021) 6744-6747. (as part of 2021 Chem Comm Emerging Investigators themed collection)
- K. Liang, R.A. Matsumoto, W. Zhao, N.C. Osti, I. Popov, B.P. Thapaliya, S. Fleischmann, S. Misra, K. Prenger, M. Tyagi, E. Mamontov, V. Augustyn, R. Unocic, A.P. Sokolov, S. Dai, P. Cummings, & M. Naguib.* “Engineering the Interlayer Spacing by Pre-Intercalation for High Performance MXene Electrodes in Room Temperature Ionic Liquid.” Advanced Functional Materials, 31 (2021) 2104007.
- W.-Y. Tsai, R. Wang, S. Boyd, V. Augustyn, & N. Balke.* “Probing Local Electrochemistry via Mechanical Cyclic Voltammetry Curves.” Nano Energy, 81 (2021) 105592.
- R. Wang, Y. Sun, A. Brady, S. Fleischmann, T. Eldred, W. Gao, H.W. Wang, D.E. Jiang, & V. Augustyn.* “Fast Proton Insertion in Layered H2W2O7 via Selective Etching of an Aurivillius Phase.” Advanced Energy Materials, 11 (2021) 2003335.
- V. Augustyn,*+ R. Wang, N. Balke, M. Pharr, & C.B. Arnold. “Deformation during Electrosorption and Insertion-type Charge Storage: Origins, Characterization, and Design of Materials for High Power.” ACS Energy Letters, 5 (2020) 3548.
- B.S. Guiton,* M. Stefik,* V. Augustyn, S. Banerjee, C.J. Bardeen, B.M. Bartlett, J. Li, V. López-Mejías, L.R. MacGillivray, A. Morris, E.E. Rodriguez, A.C.S. Samia, H. Sun, P. Sutter, & D.R. Talham. “Frontiers in Hybrid and Interfacial Materials Chemistry Research.” MRS Bulletin, 45 (2020) 951-964.
- B.B. Lynch, A.P. Kelliher, B.D. Anderson, A. Japit, M.A. Spencer, M.H. Rizvi, M.F. Sarac, V. Augustyn, & J.B. Tracy.* “Sulfidation and Selenidation of Nickel Nanoparticles.” Carbon Energy, 3 (2021) 582.
- R. Wang, S. Boyd, P.V. Bonnesen, & V. Augustyn.*+ “Effect of Water in a Non-aqueous Electrolyte on Electrochemical Mg2+ Insertion into WO3.” Journal of Power Sources, 477 (2020) 229015. (as part of Battery Community Celebration of 2019 Nobel Prize in Chemistry)
- S. Boyd, N. Geise, M.F. Toney, & V. Augustyn.*+ “High Power Energy Storage via Electrochemically Expanded and Hydrated Manganese-Rich Oxides.” Frontiers in Chemistry, 8 (2020) 715. (as part of research topic: Women in Science: Chemistry)
- S. Fleischmann, J.B. Mitchell, R. Wang, C. Zhan, D.E. Jiang, V. Presser, & V. Augustyn.*+ “Pseudocapacitance: From Fundamental Understanding to High Power Energy Storage Materials.” Chemical Reviews, 120 (2020) 6738-6782. (as part of 2020 themed issue on Beyond Li-ion Battery Chemistry)
- S. Fleischmann, M.A. Spencer, & V. Augustyn.*+ “Electrochemical Reactivity under Confinement Enabled by Molecularly Pillared 2D and Layered Materials.” Chemistry of Materials 32 (2020) 3325-3334. (as part of Up-and-Coming Perspectives)
- S. Fleischmann, Y. Sun, N.C. Osti, R. Wang, E. Mamontov, D.E. Jiang, & V. Augustyn.* “Interlayer Separation in Hydrogen Titanates Enables Electrochemical Proton Intercalation.” Journal of Materials Chemistry A 8 (2020) 412-421.
- J.B. Mitchell, N.R. Geise, A.R. Paterson, N.C. Osti, Y. Sun, S. Fleischmann, R. Zhang, L.A. Madsen, M.F. Toney, D.E. Jiang, A.I. Kolesnikov, E. Mamontov, & V. Augustyn.* “Confined Interlayer Water Promotes Structural Stability for High-Rate Electrochemical Proton Intercalation in Tungsten Oxide Hydrates.” ACS Energy Letters 4 (2019) 2805-2812.
- M.A. Spencer & V. Augustyn.*+ “Free-standing Transition Metal Oxide Electrode Architectures for Electrochemical Energy Storage.” Journal of Materials Science 54 (2019) 13045-13069.
- V. Augustyn,* M.T. McDowell,* & A. Vojvodic.* “Toward an Atomistic Understanding of Solid-State Electrochemical Interfaces for Energy Storage.” Joule 2 (2018) 2189-2193.
- S. Boyd, R. Dhall, J.M. LeBeau, & V. Augustyn.*+ “Charge Storage Mechanism and Degradation of P2-Type Sodium Transition Metal Oxides in Aqueous Electrolytes.” Journal of Materials Chemistry A 6 (2018) 22266-22276. (as part of themed collection: 2018 Journal of Materials Chemistry A Emerging Investigators)
- R. Wang, J.B. Mitchell, Q. Gao, W.-Y. Tsai, S. Boyd, M. Pharr, N. Balke, & V. Augustyn.* “Operando AFM Reveals Mechanics of Structural Water Driven Battery-to-Pseudocapacitor Transition.” ACS Nano 12 (2018) 6032-6039.
- S. Boyd & V. Augustyn.*+ “Transition Metal Oxides for Aqueous Sodium-Ion Electrochemical Energy Storage.” Inorganic Chemistry Frontiers 5 (2018) 999-1015. (as part of themed collection: Inorganic Materials for Applications in Energy and Catalysis)
- V. Augustyn*+ & Y. Gogotsi. “2D Materials with Nanoconfined Fluids for Electrochemical Energy Storage.”Joule 1 (2017) 443-452.
- S. Niu, R. McFeron, F. Godínez-Salomón, B.S. Chapman, C.A. Damin, J.B. Tracy, V. Augustyn, & C. Rhodes.* “Enhanced Electrochemical Lithium-Ion Charge Storage of Iron Oxide Nanosheets.” Chemistry of Materials 29 (2017) 7794-7807.
- R. Wang, C.-C. Chung, Y. Liu, J.L. Jones, & V. Augustyn.*+ “Electrochemical Intercalation of Mg2+ into Anhydrous and Hydrated Crystalline Tungsten Oxides.” Langmuir 33 (2017) 9314-9323. (as part of themed issue: Fundamental Interfacial Science for Energy Applications)
- J.S. Daubert, R. Wang, J.S. Ovental, H.F. Barton, R. Rajagopolan, V. Augustyn, & G.N. Parsons.* “Intrinsic Limitations of Atomic Layer Deposition for Pseudocapacitive Metal Oxides in Porous Electrochemical Capacitor Electrodes.” Journal of Materials Chemistry A 5 (2017) 13086-13097.
- J.B. Mitchell, W.C. Lo, A. Genc, J. LeBeau, & V. Augustyn.* “Transition from Battery to Pseudocapacitor Behavior via Structural Water in Tungsten Oxide.” Chemistry of Materials 29 (2017) 3928-3937.
- V. Augustyn.*+ “Tuning the Interlayer of Transition Metal Oxides for Electrochemical Energy Storage.” Journal of Materials Research 32 (2017) 2-5. (as part of themed issue: Early Career Scholars in Materials Science)
Non Peer-Reviewed Publications
- V. Augustyn.*+ “New Materials are Powering the Battery Revolution.” The Conversation. 4 October 2018.
- V. Augustyn* & J.P. Eneku. “Building the SciBridge between Africa and the United States.” AAAS Science & Diplomacy, December 2015.
Book Chapters
- R. Ding, M. Chagnot, S. Saeed, & V. Augustyn.*+ “Nanostructured Materials for Electrochemical Capacitors” in Comprehensive Inorganic Chemistry III (eds. K. Poeppelmeier & J. Reedijk, Elsevier)
- E.C. Self, D. Devendrasinh, V. Augustyn, & J. Nanda.* “An Overview of Transition Metal Oxides for Electrochemical Energy Storage” in Transition Metal Oxides for Electrochemical Energy Storage (eds. V. Augustyn & J. Nanda, Wiley-VCH GmbH).
- S. Fleischmann, I. Kamboj, & V. Augustyn.* “Nanostructured Transition Metal Oxides for Electrochemical Energy Storage” in Transition Metal Oxides for Electrochemical Energy Storage (eds. V. Augustyn & J. Nanda, Wiley-VCH GmbH).
Prior to NC State:
- V. Augustyn & A. Manthiram.* “Effects of Chemical vs. Electrochemical Delithiation on the Oxygen Evolution Reaction Activity of Nickel-rich Layered LiMO2.” The Journal of Physical Chemistry Letters 6 (2015) 3787-3791.
- V. Augustyn, S. Therese, T. Turner, & A. Manthiram.* “Nickel-Rich Layered LiNi1-xMxO2 (M = Mn, Fe, Co) Electrocatalysts with High Oxygen Evolution Reaction Activity.” Journal of Materials Chemistry A 3 (2015) 166041-6612.
- N. Colligan, V. Augustyn, & A. Manthiram.* “Evidence of Localized Lithium Removal in Layered and Spinel Li1-xCoO2 (0 ≤ x ≤ 0.9) under Oxygen Evolution Reaction Conditions.” Journal of Physical Chemistry C, 119 (2015) 2335-2340.
- V. Augustyn & A. Manthiram.* “Characterization of Layered LiMO2 Oxides for the Oxygen Evolution Reaction of Metal-Air Batteries.” ChemPlusChem 80 (2015) 422-427.
- I. E. Rauda, V. Augustyn, L. C. Saldarriaga-Lopez, X. Chen, L. T. Schelhas, G. W. Rubloff, B. Dunn, & S. H. Tolbert.* “Nanostructured Pseudocapacitors based on Atomic Layer Deposition of V2O5 onto Conductive Nanocrystal-Based Mesoporous ITO Scaffolds.” Advanced Functional Materials 24 (2014) 6717-6728.
- V. Augustyn, P. Simon, & B. Dunn.*+ “Pseudocapacitive Oxide Materials for High-Rate Electrochemical Energy Storage.” Energy & Environmental Science 7 (2014) 1597-1614.
- J. Come, V. Augustyn, J. W. Kim, P. Rozier, P.-L. Taberna, P. Gogotsi, J. W. Long, B. Dunn, & P. Simon.* “Electrochemical Kinetics of Nanostructured Nb2O5 Electrodes.” Journal of The Electrochemical Society 161 (2014) A718-A725.
- V. Augustyn, E. R. White, J. Ko, G. Grüner, B. C. Regan, & B. Dunn.* “Lithium-Ion Storage Properties of Titanium Oxide Nanosheets.” Materials Horizons 1 (2014) 219-223.
- V. Augustyn, J. Come, M. A. Lowe, J. W. Kim, P.-L. Taberna, S. H. Tolbert, H. D. Abruña, P. Simon, & B. Dunn.* “High Rate Electrochemical Energy Storage via Li+ Intercalation Pseudocapacitance.” Nature Materials 12 (2013) 518-522.
- I. Rauda, V. Augustyn, B. Dunn, & S. H. Tolbert.* “Enhancing Pseudocapacitive Charge Storage in Polymer Templated Mesoporous Materials.” Accounts of Chemical Research 46 (2013) 1113-1124.
- V. Augustyn & B. Dunn.* “Low-Potential Lithium-Ion Reactivity of Vanadium Oxide Aerogels.” Electrochimica Acta, 88 (2013) 530-535.
- M. Hmadeh, Z. Lu, Z. Liu, F. Gándara, H. Furukawa, S. Wan, V. Augustyn, R. Chang, L. Liao, F. Zhou, E. Perre, V. Ozolins, X. Duan, B. Dunn, Y. Yamamoto, O. Terasaki, & O. M. Yaghi.* “New Porous Crystals of Extended Metal-Catecholates.” Chemistry of Materials 24 (2012) 3511-3513.
- I. Rauda, R. Buonsanti, L. C. Saldarriaga-Lopez, K. Benjauthrit, L. T. Schelhas, M. M. Stefik, V. Augustyn, J. Ko, B. Dunn, U. Wiesner, D. J. Milliron, & S. H. Tolbert.* “A General Method for the Synthesis of Hierarchical Nanocrystal-Based Mesoporous Materials.” ACS Nano 6 (2012) 6386-6399.
- E. R. White, S. B. Singer, V. Augustyn, W. A. Hubbard, M. Mecklenburg, B. Dunn, & B. C. Regan.* “In Situ Transmission Electron Microscopy of Lead Dendrites and Lead Ions in Aqueous Solution.” ACS Nano 6 (2012) 6308-6317.
- Z. Chen, V. Augustyn, X. Jia, Q. Xiao, B. Dunn, & Y. F. Lu.* “High-Performance Sodium-Ion Pseudocapacitors Based on Hierarchically Porous Nanowire Composites.” ACS Nano 6 (2012) 4319-4327.
- J. W. Kim, V. Augustyn, & B. Dunn.* “The Effect of Crystallinity on the Rapid Pseudocapacitive Response of Nb2O5.” Advanced Energy Materials 2 (2012) 141-148.
- X. Wang, G. Li, Z. Chen, V. Augustyn, X. Ma, G. Wang, B. Dunn, & Y. F. Lu.* “High-Performance Supercapacitors Based on Nanocomposites of Nb2O5 Nanocrystals and Carbon Nanotubes.” Advanced Energy Materials 1 (2011) 1089-1093.
- Z. Chen, V. Augustyn, J. Wen, Y. W. Zhang, M. Q. Shen, B. Dunn, & Y. F. Lu.* “High-Performance Supercapacitors Based on Intertwined CNT/V2O5 Nanowire Nanocomposites.” Advanced Materials 23 (2011) 791-795.
- V. Augustyn & B. Dunn.*+ “Vanadium Oxide Aerogels: Nanostructured Materials for Enhanced Energy Storage.” Comptes Rendus Chimie 13 (2010) 130-141.